Remove burner assembly.
Hot water heater thermocouple replacement.
Then unfasten the three nuts that hold the thermocouple and the two gas tubes to the valve.
The thermocouple is a heat sensitive device that sends an electrical signal to the gas valve to keep the pilot valve open when the pilot is on.
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Apply soapy water around the three fittings looking for bubbles that indicate a gas leak.
Turn the gas on leading to the water heater.
It also signals the valve to close when the pilot.
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How to replace the thermocouple on a standing pilot water heater.
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The thermocouple is usually attached to the pilot gas supply tube with one or more clips that snap into place.
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Perhaps you need a new pilot or igniter.
First shut off the gas valve on the water heater and the gas valve on the gas line near the heater.
Re light the pilot according to the instructions printed on it and set the temperature control valve to the desired temperature.
Take the detached thermocouple with you to the home center or hardware store and buy a new one.
The burner typically sits loosely or under clips in the burning chamber and just slides out.
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Detach the thermocouple from the burner.
A thermocouple thermopile or thermostat.
Once the pilot supply tube burner supply tube and thermocouple are disconnected from the gas control valve see above simply lift and remove the burner assembly from the bottom of the water heater.